
Not many surprises in the Copa del Rey outside of the shocking elimination of Real Madrid at home to third division side Alcorcón. Bojan Krkic scored a brace in one minute, Lio Messi scored three minutes after stepping onto the pitch and made academic entertaining in the second half of their match against Cultural Leonesa.
Altético seemed to get a limited amount of solace after losing the Madrid derby. They went out and punished Marbella thanks to four goals by Maxi Rodríguez. Italian-American forward Giuseppe Rossi was the difference maker for Villarreal as the Yellow Submarine continued in the race for the king's cup beating Puertollano 1-0 at El Madrigal.
| Real Madrid | 1-0 | Alcorcón | ALC adv. on 1-4 agg. |
| Barcelona | 5-0 | Cultural Leonesa | BAR adv. on 7-0 agg. |
| Villarreal | 1-0 | Puertollano | VIL adv. on 2-1 agg. |
| Valencia | 2-2 | Alcoyano | VAL adv. on 3-2 agg. |
| Atlético | 6-0 | Marbella | ATM adv. on 8-0 agg |
| Málaga | 0-0 | Zaragoza | MAL adv. on away goals |
| Osasuna | 1-0 | Xerez | OSA adv. on 3-1 agg. |
| Deportivo | 0-0 | Murica | DEP adv. on 1-0 agg. |
| Tenerife | 0-1 | Celta | CEL adv. on 1-3 agg. |
| Sevilla | 5-0 | C. de Lorquí | SEV adv. on 9-2 agg |
| Sporting | 1-1 | Recreativo | REC adv. on PKs 4-2 |