The latest envelop was reported on Tuesday morning at the German mission. The other three arrived Monday at the missions of France, Austria and Uzbekistan.
Paul Browne, a spokesman for the New York Police Department, says all four envelopes had Dallas, Texas, postmarks, and at least one contained a note referring to al-Qaida.
Richard Kolko, an FBI spokesman, says his office is trying to locate the sender.
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As a precaution, hazardous material units decontaminated employees who handled the envelopes.
Austria's U.N. ambassador, Thomas Mayr-Harting, says work at his mission is almost back to normal.
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